Delayed ettringite formation delayed ettringite formation is a less common, but potentially more damaging, cause of distress than asr. Delayed ettringite formation an overview sciencedirect topics. The disruptive effect is due to the nonuniform expansion localized only in the area of the concrete structure where ettringite forms. It can take up to 20 years for cracking to become apparent. Ettringite is also known as c ement bacillus, which is the name of a naturally occurring mineral of the same composition and structure. Ettringite formation and the performance of concrete portland. There have been far fewer documented cases of def than of asr, and prior to this project, there were no published cases in which def was the sole culprit in causing deterioration in an actual field structure. Ettringite formation and sulfate attack on concrete.
Def is defined as the formation of ettringite in a concrete after setting, and without any external sulphate supply but with water supply. Wje was requested to investigate the possible effect of the reported elevated temperature on the durability of this major structure with a 100year design service life. For a pavement that is experiencing accelerated deterioration due to delayed ettringite formation, and that is near a minimum service level condition i. Characterization of delayed ettringite formation using. Sulfate attack is particularly complex because the source of sulfates can be external or internal delayed ettringite formation, and the distress can be chemical in nature, due to alteration of hydration of products, or physical in nature, due to phase changes in the penetrating. An experimental clarification of the association of delayed ettringite formation with alkaliaggregate reaction. The modernized delayed benoni modernized reti benoni benoni defense modern benoni the modernized reti, a complete repertoire for white 771. It has been proposed that def expansion is affected by. Delayed ettringite formation def is expansion and cracking of concrete associated with the delayed formation of the mineral ettringite which is a normal product of early cement hydration. A nondestructive acoustic approach for the detection and quantification of damage in mortars affected by delayed ettringite formation def is used to study the degradation mechanism at micro and macroscales. Evaluation for the potential of delayed ettringite formation charts generated by thermocouples cast into the affected concrete measured curing temperatures of significantly in excess of the.
Based on the experience of the writer and others, def is to be expected in both steam. Delayed ettnngite formation def is an endogenous reaction which can cause deterioration in concrete. The modernized delayed benoni modernized reti benoni benoni defense modern benoni the modernized reti, a. Mortars made from cements with sulphate levels of 3%. Pathology, assessment and treatment of structures affected. Sulfate attack is a complex form of deterioration that has damaged concrete structures throughout the world. Delayed ettringite formation aci concrete code issues.
Claims that slow release of sulfate from the clinker can have a similar effect in concrete not thus heated are unsupported. Delayed ettringite formation def is a chemical reaction with proven damaging effects on the mechanical properties of hydrated cementitious. With many large scale civil engineering construction projects being undertaken, there is a possibility to find large concrete pours in thick members. Due to the hydration process, temperatures in concrete will increase during early stages and when the temperature exceeds 70 0 c, delayed ettringite formation def can take place. Mpa cement fact sheet 3 delayed etttringite formation in. Characterization of delayed ettringite formation in maryland. Mechanisms affecting the delayed efficiency of cement. An external source of sulfur is not required for this type of early pcc deterioration to occur. Cracks due to delayed ettringite formation civildigital.
Delayed ettringite formation an overview sciencedirect. Diagnosing delayed ettringite formation in concrete. Delayed ettringite formation in concrete jochen stark, katrin bollmann bauhausuniversity weimar germany 1. Delayed ettringite formation processes and problems. This experimental study aims to determine the effect of relative humidity on concrete expansion due to delayed ettringite formation def, which still remains imperfectly known. Claims that slow release of sulfate from the clinker can have a similar effect. Characterization of damage in mortar and concrete specimens.
Delayed ettringite formation def is a special case of internal sulfate attack. Controlling ettringite formation recommended practice for. This delayed ettringite formation may result in the decrease of resistance of portland cement concrete to chloride penetration. Delayed ettringite formation has been a significant problem in many countries. The cause for these failures has been identified as delayed ettringite attack, a process whereby the normal formation of ettringite in plastic portland cement concrete is either delayed or is. Pdf delayed ettringite formation fami fami academia. Delayed ettringite formation def occurs at late ages and the related heterogeneous expansion in a very rigid hardened concrete can produce cracking and spalling. To fulfil the aim of this study, a portion of cement was replaced by class ffly ash, with three. This implies that if excessive soluble sulfate contents in cements were available, it would be reasonable to expect field problems in concrete made from that cement to show up relatively early in the life of the structure, probably. Delayed ettringite formation def in cementitious materials is considered as a harmful chemical reaction leading to a variety of damages. In this paper, the effect of fly ash on delayed ettringite formation of heatcured cementbased mortars was investigated.
Nondestructive evaluation of inservice concrete structures. Delayed ettringite formation def can affect the longterm durability of concrete structures by causing cracking and expansion of the material. Delayed ettringite formation def is expansion and cracking of concrete associated with the delayed formation of the mineral ettringite which is a normal product of early cement. The effect of the partial cement substitution with fly ash on. As discussed above, high content of alkalis will lead to less quantities of early ettringite formed, thus. Collepardi civil engineering faculty, leonardo da vinci, politechnic milan, italy abstract. Delayed ettringite formation is still an open question. Pdf during the hydration of cement, tricalcium aluminate c3a reacts with gypsum and forms ettringite aft. Pdf delayed ettringite formation in fly ash concrete under moist. Pdf charactherization of delayed ettringite formation in. It is a normal product in concrete and is delayed when the temperature rises too high for it to form.
Delayed ettringite formation s s s s s s s s a a a a a a a a alumina s sulfate ettringite cement grain csh water water water occurs when fresh concrete is heated above a temperature of 158f. The research investigated the significance of delayed ettringite formation def. Delayed ettringite formation, cement and concrete research. Blast furnace slag addition effects on delayed ettringite formation. Mathematical modeling of the pessimum action of chlorides on the extent of delayed ettringite formation. Lehmann, for an occurrence near the ettringer bellerberg volcano, ettringen, rheinlandpfalz, germany. Damage due to the delayed ettringite formation allegedly occurs when material is exposed to temperatures higher than 70c 3,4. Pathology, assessment and treatment of structures affected by. Delayed ettringite formation def in concrete is likely to lead to swelling and cracking in structures which have undergone early age heating to a temperature of over 65 c. A test method to determine the expansion potential, due to delayed ettringite formation def, of portland.
Characterization of delayed ettringite formation using nonlinear impact resonance spectroscopy method. Delayed ettringite formation is a consequence of improper heating during the curing process. Study of asraffected and defaffected structures as well as testing and evaluation results of eliminating components. May 01, 2001 delayed ettringite formation def can damage concrete that has experienced a temperature above about 70c. Delayed ettringite formation def is a possible autogenous expansive reaction of concrete. Strategies for prevention of delayed ettringite formation in. At the present time, there is no selective and predictive test for def this paper describes the results of a study aimed at developing a test based on drying and wetting cycles. Delayed ettringite formation a concern for precast concrete. The formation of ettringite or cement bacillus has been. Significance of delayed ettringite formation and damage.
Qualitative and quantitative analyses for ettringite, including xray diffraction xrd and differential thermal analysis dta. The formation of ettringite or cement bacillus has been recognized as the cause of excessive expansion, cracking and even complete disintegration of concrete subjected to intensive sulfate attack. Civil engineering faculty, leonardo da vinci, politechnic. As discussed above, high content of alkalis will lead to less quantities of early ettringite formed, thus resulting in higher sulphate contents being available for reaction later to form delayed ettringite. Preventing alkalisilica reaction and delayed ettringite. Mineral additives used as partial cement replacement should help in achieving the desired aspect.
The term premature concrete deterioration pcd has been adopted to refer to problems associated with asr and def because it is often difficult to distinguish between them. Def causes a characteristic form of damage which is highly influenced by the cement chemistry, curing methods and exposure conditions. Procedures for quantifying the potential degree of future def development in concrete, using accelerated hydration and dta determination of any additional ettringite developed. Def is a result of high early temperatures above 70 o c 80 o c in the concrete which prevents the normal formation of ettringite.
Delayed ettringite formation is a relatively rare and controversial phenomenon in concrete deterioration, strongly related to the practice of heat curing. Delayed ettringite formation def is known as the deterioration phenomenon that occurs in mortar or concrete cured at high temperature. When ettringite forms later after several months or years def the related heterogeneous expansion in a very rigid hardened concrete can produce cracking. Investigation of the internal stresses caused by delayed. Moist map cracking, a suggested defrelated damage, appears to be correlated with lamellar ettringite formations and high quantities of def with in the concrete. The mechanism of expansion is still the subject of research. On the delayed expansion of heat cured portland cement pastes and concretes. Blast furnace slag addition effects on delayed ettringite. It also occurs as weathering crusts on larnite in the hatrurim formation. It occurs within metamorphically altered limestone adjacent to igneous intrusive rocks or within xenoliths. Accelerated test for measuring sulfate resistance of. Cracks due to delayed ettringite formation civildigital civil engineering articles civil engineering articles for mobile significance of delayed ettringite formation and damage. High temperature curing of concrete long beach, ca wje. Introduction the problem of durability of concrete with cement as binding.
The purpose of extending mellowing time before compaction in soils is to force ettringite formation prior to compaction of pavement layers. Mathematical modeling of the pessimum action of chlorides. Delayed ettringite formation def is sometimes called an internal sulfate attack. The molar ratios of so 3 al 2 o 3 in both cements are less than 0. The most important form of internal sulfate attack is delayed ettringite formation def. This delayed ettringite formation may result in the decrease of resistance of portland. Delayed ettringite formation def in concrete and mortar systems has been associated with deleterious expansion leading to its premature deterioration. A test method to determine the expansion potential, due to delayed ettringite formation def, of portland cements initially moistcured at high temperatures was developed. Examples of sulfate attack include ettringite formation, delayed ettringite formation, and thaumasite formation hobbs, 2001.
Ettringite or hydrated calcium aluminum sulfate hydroxide ca 6 al 2 so 4 3 oh 12 26h 2 o is formed by the reaction between sulfate ions and the aluminate phases in cement. Types and causes of cracking in concrete structures. When ettringite forms later after several months or years def the related heterogeneous expansion in a very rigid hardened concrete can produce cracking and spalling. The volume of the formed def crystals in the hardened concrete is larger than the volume of reactants, which results in forces from the growing crystals acting upon the walls of the crack. Edges and corners are particularly vulnerable, and a friable concrete surface results figure 8.
Introduction the problem of durability of concrete with cement as binding material comes more and more to the fore with the increased use of concrete, with the changed production and utilization. Expansion of cement mortars made with eight different portland cements was investigated. The combination of mellowing time and moisture content that achieves this goal is selected. In turn, the durability of concrete structures can often be affected by chemical attacks, endangering its performance and safety. Def is a result of high early temperatures above 70 o c 80 o c in the concrete which prevents the normal formation. Jun 01, 2008 diagnosing delayed ettringite formation in concrete structures diagnosing delayed ettringite formation in concrete structures thomas, michael. Growth of ettringite crystals opens the crack and damages the cement products. Precastprestressed concrete institute, manual for quality control. Mpa cement fact sheet 3 introduction def has caused cracking in some heat cured precast concrete components many years after the concrete was produced. The effect of delayed ettringite formation on fine grained.
This information paper, which is mainly concerned with insitu concrete, identifies circumstances in which def may cause problems. Characterization of delayed ettringite formation in maryland bridges. Claims that slow release of sulfate from the clinker can have a. Defrelated expansion of concrete as a function of sulfate. Delayed ettringite formation in portland cement products. Expansion results from formation of ettringite crystals of submicrometre size in the paste, the larger. Delayed ettringite formation, favored by the high sulfate content of fly ashes and contrasted by the low sulfate content of natural.
It is only damaging to concrete cured under low temperatures, where it forms more slowly, or high temperatures which may delay the formation of ettringite. Influence of relative humidity on delayed ettringite formation. Formulation pelmane lenge mulongo1,a, stephen ekolu1,b 1cement and. Risk analysis of the delayed ettringite formation in pile. Reducing expansion due to delayed ettringite formation def is becoming an important issue that must be taken into account, when producing heatcured concrete. The two main chemicals attacks to concrete are attributed to alkaliaggregate reaction aar and the action of sulphates, among which stands out the delayed ettringite formation def delayed ettringite formation. It can affect materials that have experienced temperatures higher than about 65 c at early age. Fu, delayed ettringite formation in portland cement products, phd thesis, department of civil engineering, university of ottawa, ottawa, 1996. This information paper, which is mainly concerned with insitu concrete, identifies the circumstances in which delayed ettringite formation may cause problems. Water is a critical element in the formation of ettringite. The formation of ettringite in the fresh, plastic concrete is the mechanism that controls stiffening. Reducing expansion due to delayed ettringite formation def is becoming an important issue that. Charactherization of delayed ettringite formation in maryland bridges complete project report pdf.
Download charactherization of delayed ettringite formation in maryland bridges complete project report. Based on an ongoing experimental program, this research emphasizes on the effect of blast furnace slag bfs on the expansion of cement. Significance of delayed ettringite formation and damage mechanisms the primary ettringite formation in the initial stage of the hydration is seen as a positive effect because it read more. Abstractexpansive internal sulphate reaction of concrete due to delayed ettringite formation def can damage concrete structures severely. Ettringite formation and the performance of concrete. Alkalisilica reaction and delayed ettringite formation. Chemical and petrographic analyses and astm test procedures. Delayed ettringite formation archives civildigital. A kinetic model for prediction of cement susceptibility to. Aci committee 201, guide to durable concrete, aci manual of concrete. Heat curing and delayed ettringite formation mrs online.
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